When Cleopatra dissolved pearls of wondrous value in vinegar, she was exhibiting unwittingly an instance of chemical elective affinity; the pearl being simply carbonate of lime, which was decomposed by the greater affinity or fondness of lime for its new acquaintance (the acetic acid of the vinegar) than for the carbonic acid, with which it had been united all its life,--an example of inconstancy in strong contrast with the conduct of its owner, who chose death rather than become the mistress of her lover"s conqueror.
GASES.
The three permanent gaseous elements are oxygen, hydrogen, and nitrogen.
The compound gases are very numerous, some being combustible, and others supporters of combustion.
Gases are for the most part transparent and colourless, with a few exceptions, and of course, like the air of the atmosphere, invisible.
They are little affected by the attraction of cohesion, but rather, on the contrary, the particles composing them have a constant tendency to separate from each other, so that their force of expansion is only limited by the pressure under which they may be kept, and the temperature they may be exposed to. They have a tendency to _penetrate_ each other, as it were; for instance, if you take a jar of heavy gas, such as carbonic gas, set it with its mouth upwards, then invert over it another jar containing hydrogen, a gas nearly twenty-two times lighter; in a very short time the two gases will have become thoroughly mixed, the heavy carbonic acid having risen, and the light hydrogen fallen, until the gases are thoroughly mixed, each jar containing an equal quant.i.ty of each gas.
OXYGEN GAS.
This gas, so named from two Greek words signifying the maker of acid, was discovered by Dr. Priestly in 1774. He obtained it by heating the red oxide of mercury in a gla.s.s retort, when the gas escaped in considerable quant.i.ties. In the ensuing year Scheele obtained it by a variety of methods, and a few years afterwards Lavoisier discovered that it was contained in atmospheric air, where it exists in the proportion of about one-fifth, the remaining four-fifths being almost entirely nitrogen.
Oxygen gas may be obtained for the purpose of experiment, by heating to redness the black oxide of manganese in an iron bottle, to the mouth of which a flexible tube is attached to convey away the gas as fast as it is liberated from the manganese. The first portions should be allowed to escape, being mixed with the air in the tubes and bottle, and the remainder may be collected in a gasometer, or in gla.s.s jars inverted over water.
Another method to obtain the gas, and one to be used only in the absence of other ingredients, is to mix in a retort some of this same oxide of manganese with about half its weight of strong sulphuric acid, and apply heat to the retort, when the gas will come over in considerable quant.i.ties; the first portions must be allowed to escape as before.[6]
If the gas is required _very_ pure, a small quant.i.ty of the salt called chlorate of pota.s.sa may be heated in a retort, and oxygen gas will be evolved, and may be collected as before. If you have an iron bottle, the first mode is by far the cheapest, as the heat of a bright fire is sufficient for the operation, and a large quant.i.ty of gas is obtained in a short time from a very inexpensive material. The most rapid and convenient process of all is to heat a mixture of two parts chlorate of potash, and one of powdered black oxide of manganese, in a common clean oil flask, to which a cork and bent tube has been adapted. Care must be taken not to mistake sulphide of antimony for black oxide of manganese, as very serious accidents have arisen from this cause.
[6] Some _boiling_ water should be added to the ma.s.s left in the retort directly the gas has ceased to come away, or it will adhere to the gla.s.s so firmly, that the retort will certainly be spoilt.
Oxygen is largely distributed over our globe, both in its uncombined state, and in union with other substances. Besides forming one-fifth of the atmosphere, it forms eight-ninths by weight of all the water in the ocean, rivers, and springs on the face of the whole earth. It also, in combination with various metals, forms the various earths and minerals of which the crust of the earth consists, so that it is the most abundant and widely distributed substance in nature, and in combination with other elements, forms nearly half the weight of the solid earth.
In its uncombined state it is a colourless gas, somewhat heavier than atmospheric air, without taste or smell. It is a powerful supporter of combustion, and is absolutely necessary for the support of animal life, which cannot exist for any time without a free supply of this gas, which is constantly consumed in the act of breathing, and is replaced by an equivalent portion of carbonic acid gas. The want of oxygen is partly the cause of the oppression felt in crowded rooms, where the air cannot be renewed so fast as is required for the number of persons who are constantly consuming the oxygen; and if an animal be confined under a gla.s.s jar inverted over water, it will presently die, just for the same reason that burning tapers are extinguished under similar circ.u.mstances.
If a jet of this gas be thrown upon a piece of charcoal, sulphur, or almost any combustible body in a state of ignition, it will make it burn with great vividness and rapidity. For a complete series of experiments with oxygen see "The Boy"s Play-book of Science."
EXPERIMENT.
But by far the most intense heat, and most brilliant light, may be produced by introducing a piece of phosphorus into a jar of oxygen. The phosphorus may be placed in a small copper cup, with a long handle of thick wire pa.s.sing through a hole in a cork that fits the jar. The phosphorus must first be ignited; and, as soon as it is introduced into the oxygen, it gives out a light so brilliant that no eye can bear it, and the whole jar appears filled with an intensely luminous atmosphere.
It is well to dilute the oxygen with about one-fourth part of common air to moderate the intense heat which is nearly certain to break the jar if pure oxygen is used.
[Ill.u.s.tration]
EXPERIMENT.
If a piece of charcoal, which is pure carbon or nearly so, be ignited, and introduced into a jar containing oxygen or common atmospheric air, the product will be carbonic gas only, of which we shall speak presently. As most combustible bodies contain both carbon and hydrogen, the result of their combination is carbonic acid and water. This is the case with the gas used for illumination; and in order to prevent the water so produced from spoiling goods in shops, various plans have been devised for carrying off the water when in the state of steam. This is generally accomplished by suspending over the burners gla.s.s bells, communicating with tubes opening into the chimney, or pa.s.sing outside the house.
To show that oxygen, or some equivalent, is necessary for the support of combustion, fix two or three pieces of wax-taper on flat pieces of cork, and set them floating on water in a soup-plate, light them, and invert over them a gla.s.s jar; as they burn, the heat produced may perhaps at first expand the air so as to force a small quant.i.ty out of the jar, but the water will soon rise in the jar, and continue to do so until the tapers expire, when you will find that a considerable portion of the air has disappeared, and what remains will no longer support flame; that is, the oxygen has been converted partly into water, and partly into carbonic acid gas, by uniting with the carbon and hydrogen, of which the taper consists, and the remaining air is princ.i.p.ally nitrogen, with some carbonic acid; the presence of the latter may be proved by decanting some of the remaining air into a bottle, and then shaking some lime-water with it, which will absorb the carbonic acid and form chalk, rendering the water quite turbid.
NITROGEN.
This gas is, as its name implies, the producer of nitre, or at least forms a portion of the nitric acid contained in nitre. It is rather lighter than atmospheric air, colourless, transparent, incapable of supporting animal life, on which account it is sometimes called azote--an objectionable name, as it is not a poison like many other gases, but destroys life only in the absence of oxygen. This gas extinguishes all burning bodies plunged into it, and does not itself burn. It exists largely in nature, for four-fifths of the atmosphere consists of nitrogen gas. It is also an important const.i.tuent of animal bodies, and is found in the vegetable world.
Nitrogen may be most easily obtained for experiment by setting fire to some phosphorus contained in a porcelain or metallic cup, placed under a gas jar full of air, and resting on the shelf of the pneumatic trough, or in a soup-plate filled with water.
Nitrogen combines in five different proportions with oxygen, producing five distinct chemical compounds, named respectively nitrous oxide, nitric oxide, nitric tri-oxide, nitric tetr-oxide, nitric pent-oxide, which last, united with water, forms nitric acid, now called hydric nitrate, as nitrous acid is termed hydric nitrite.
[Ill.u.s.tration]
Nitrous oxide gas is generally known by the name of "laughing gas," from the jolly sensations experienced on inhaling it. It may be procured by distilling in a gla.s.s retort a salt called nitrate of ammonia, which yields the gas in considerable quant.i.ties, and it should be kept standing in jars over water for some hours before it is used. It should be transferred into a silk air-tight bag, furnished with a stopc.o.c.k and mouthpiece, from which the gas may be breathed; a little practice is required to do this easily, and more resolution to desist when the gas begins to produce its effects, as it appears to fascinate the experimenter, and actual force is often necessary to remove the bag from the mouth. The effects produced vary according to the temperament of the person inhaling it; they are, however, always of a highly pleasurable nature, muscular action being generally greatly exalted, compelling the individual to race round the apartment and execute leaps and pirouettes perfectly astounding. Some persons shout and sing, and I have seen one expend his superfluous animation in twisting his features into such ludicrous grimaces as would be the envy of the candidates at a grinning match, and beat them all out of the field. Sir H. Davy was the discoverer of this gas, and of its peculiar effects on the nervous system, and a full account of it may be found in his "Researches on Nitrous Oxide Gas."
This gas is heavier than air, and supports combustion nearly as energetically as oxygen, as may be shown by introducing a piece of ignited phosphorus into a jar of this gas. It will not, however, support the life of small animals, such as mice, which introduced into it die very quickly.
[Ill.u.s.tration: PLAN OF PNEUMATIC TROUGH.]
[Ill.u.s.tration: SECTION OF PNEUMATIC TROUGH.]
The next compound of nitrogen with oxygen, when one proportion of nitrogen unites with two of oxygen, is termed nit_ric_ oxide gas. It may be easily procured by heating in a retort some copper turnings in dilute nitric acid. It is colourless and transparent, and has the property of combining with oxygen to form other compounds.
EXPERIMENT.
Into a jar of this gas standing over water pa.s.s some oxygen gas. The jar will be filled with red fumes, which will be rapidly absorbed by the water. If atmospheric air be used instead of oxygen, there will remain in the jar the nitrogen of the air, amounting to four-fifths of the air employed.
This gas is destructive to animal life, in consequence of its property of uniting with the oxygen in the lungs, and producing the highly corrosive nitrous acid gas. It will, however, support the combustion of a few substances, phosphorus for instance, provided it is sufficiently heated before being plunged into the gas.
We pa.s.s over the third and fourth compounds of nitrogen with oxygen, as they are not calculated for amusing experiments. Nitric acid is easily prepared on the small scale, by gradually heating equal parts by weight of nitric and sulphuric acid in a retort to which a receiver has been adapted. The receiver, which may be a clean oil flask, should be kept cool with wetted blotting paper.
Nitrogen combines with chlorine and iodine, forming detonating compounds, the former being so extremely dangerous that it will be better to pa.s.s it by.
The compound with iodine, called iodide of nitrogen, may very easily be made by pouring strong solution of ammonia (a compound of nitrogen and hydrogen) upon some iodine in a phial, shaking them well together, and after letting them stand for a few hours, pouring off the fluid; the black powder remaining in the phial is the explosive compound, the iodide of nitrogen. When dry, it is very apt to detonate spontaneously; it should therefore be shaken out of the phial while _wet_, and spread in very small quant.i.ties on separate pieces of blotting paper, which should be kept apart from each other. When thoroughly dry, the slightest touch with the point of a feather, shaking the paper on which it rests, or even opening too rapidly the door of a closet where it has been put to dry, will cause it to explode, producing a quant.i.ty of violet-coloured fumes. The explosion is somewhat violent, producing a sharp cracking noise; and the greatest care should be taken in experimenting with it.
ATMOSPHERIC AIR.
As has been already mentioned, nitrogen is the princ.i.p.al const.i.tuent of the air of the atmosphere which surrounds our globe, extending to a height of about forty-five miles above it, and playing a most important part in the economy of nature, inorganic as well as organic.
This atmospheric air consists by volume of nearly four-fifths of nitrogen, and rather more than one-fifth of oxygen, viz. seventy-nine of the former to twenty-one of the latter, or twenty-three parts by weight of oxygen and seventy-seven of nitrogen; it generally contains also a variable proportion of the vapour of water, and a very small quant.i.ty of carbonic acid gas, being only about four volumes to 10,000 of air. Its const.i.tuent parts are easily separated, as it is a mechanical mixture and not a chemical compound, though the mixture by diffusion is so complete that chemists have not been able to ascertain any difference in the composition of air taken from all parts of the world, and from different heights, up to the highest point which has to this time been attained.
The atmosphere presses on the surface of the globe, and every being on it, with a force of about fifteen pounds to every square inch of surface, but as it presses equally in all directions, upwards as well as downwards, its weight cannot be perceived unless the pressure be removed from one surface by some artificial means.
Atmospheric air contains, besides the oxygen and nitrogen, its princ.i.p.al const.i.tuents, a small proportion of carbonic acid gas, as has been mentioned, and this may be shown by filling a tube about half full of lime-water, and shaking it with the air contained in the other half, when it will become slightly turbid from the insoluble carbonate of lime formed.
When we consider that every living animal is constantly consuming oxygen, and replacing it by carbonic acid gas, and that all burning bodies, fires in our dwellings, furnaces, artificial lights of all kinds, act in the same way in abstracting the oxygen from the air, and replacing it by immense quant.i.ties of carbonic acid gas, which is a poison to all animals who breathe, or attempt to breathe it, we must wonder what becomes of this irrespirable gas, as it is found to exist in the air in quant.i.ties so minute, and by what means the oxygen is restored, and the air again made fit for respiration. This is effected by one of those laws which the wisdom of the Creator has impressed upon matter, by which one part of creation as it were balances another, and all proceeds in an endless circle of change. This carbonic acid, which is so poisonous to animal life, is the food of the vegetable world, plants having the power of taking up the carbonic acid into their pores; converting the carbon into their own substance, and rejecting the oxygen, which is again respired by animals, &c. In the same way, all animal refuse is the food of vegetables, and is used under the name of manures.
The atmosphere contains also a variable quant.i.ty of vapour of water, invisible as long as it is in the state of vapour, but it may be rendered obvious by bringing any very cold body into warm air, when the vapour will condense on the cold body in the form of small drops of water. A tumbler of fresh-pumped water brought into a crowded room, is almost immediately covered with moisture, and it may also be seen on bottles of wine which have been put into ice before coming to table.
Fogs are occasioned by the condensation of vapour produced by mixing a current of warm air with a colder air. The banks of Newfoundland are notorious for dense fogs, occasioned by the warm air brought from the south by the great Gulf stream, mixing with the cold air from the Arctic regions, and thus precipitating the vapour in a visible form, rendering everything but itself invisible. The famous London fogs depend upon the same precipitation of the vapour of water, with the addition of the smoke from the numerous sea-coal fires, which give it that interesting yellow tinge for which it is so remarkable.
Aqueous vapour appears to impart a transparency to air, and permits objects to be seen more distinctly in proportion to its quant.i.ty; hence, when distant hills appear nearer, and objects upon them more distinct than usual, rain may be expected, the air being fully charged with vapour ready to be deposited on the slightest cause.
HYDROGEN.