It may seem curious to the reader that we should care to discuss a subject seemingly so simple as common salt. But it is a very usual thing for us to live and move in the presence of things that are very common to our everyday experience, and yet know scarcely anything about them, beyond the fact that they in some way serve our purpose.
Salt is one of the commonest articles used in the preparation of our food. It has been questioned by some people whether salt was a real necessity as an animal food, or whether the taste for it is merely an acquired one. All peoples in all ages seem to have used salt, and reference to it is made in the earliest histories. Travelers tell us that savage tribes, wherever they exist, are as much addicted to the use of salt as civilized people. One of the early African travelers, Mungo Park, tells us that the children of central Africa will suck a piece of rock salt with the same avidity and seeming satisfaction as the ordinary civilized child will a lump of sugar.
All animals seem to require salt, and it is claimed by those who have tried the experiment that after one has refrained from the use of salt for a certain length of time the craving for it becomes exceedingly painful. It is most likely that the taste for salt is a natural craving.
In any event, whether it is a natural or an artificial taste, it has become an article of the greatest importance in the preparation of food, as well as on account of its use in the arts. Salt is a compound of chlorine and sodium. In chemical language it is called sodium chloride.
The symbol is NaCl, which means that a molecule of salt is composed of one atom of sodium and one of chlorine. Chlorine is an exceedingly poisonous gas.
Formerly the chemist when he wished to obtain sodium extracted it from common salt and discharged the chlorine gas into the air. It was found that in establishments where the manufacture of sodium was conducted on a large scale the destructive properties of the chlorine discharged into the air was such that all vegetation was killed for some distance around the manufactory. This came to be such a nuisance that the manufacturers were either compelled to stop business or in some way take care of the chlorine. This is done at the present day by uniting the chlorine gas with common lime, forming a chloride of lime, which is used for bleaching and purifying purposes.
Salt is found in great quant.i.ties as a natural product under the name of rock salt. It is found in some parts of the world in great veins over 100 feet in thickness. In some cases the rock salt is mined, when it has to be purified for commercial purposes. The common mode of obtaining salt, however, is by pumping the solution from these great beds where it is mingled with water--salt water; the water is then evaporated, and when it reaches a certain stage of evaporation the salt crystallizes and falls to the bottom.
Different substances crystallize in different forms. The crystallization of water when it freezes, as we shall see hereafter, arranges its molecules in such a form as to make a lump of ice of given dimensions lighter than the same dimensions of water would be. Salt in crystallizing does not follow the same law; the salt crystal is in the shape of a cube and is denser in its crystalline form than in solution, hence it is heavier and falls to the bottom.
It is said that there is a deposit of rock salt in Galicia, Austria, covering an area of 10,000 square miles. There are also very large deposits in England, the mining of which has become a great industry.
There are also great beds of salt in various parts of the United States, notably near Syracuse, N. Y., where large salt deposits were exposed in an old river bed formed in preglacial times. The common mode of preparing salt for domestic purposes is by the process of evaporation from brine that has been pumped from salt wells. The quality of the salt is determined largely by the temperature at the time of evaporating the water from it. Ordinary coa.r.s.e salt, such as is used for preserving meat or fish, is made at a temperature of about 110 degrees; what is known as common salt is made at a temperature of about 175 degrees; while common fine or table salt is made at a temperature of 220 degrees. Thus it will be seen that the process of granulation with reference to its fineness is determined by the rapidity of evaporation. Salt is one of the princ.i.p.al agents in preserving all kinds of meats against putrefaction.
It will also preserve wood against dry rot. Vessel builders make use of this fact to preserve the timbers used in the construction of the vessels.
Salt at the present day is very cheap, but at the beginning of the present century it was worth from $60 to $70 per ton. The methods of decomposing salt to obtain its const.i.tuents, which are used in various other compounds, are very simple to-day as compared with the processes that prevailed in the days before the advent of electricity in large volume, such as is produced by the power of Niagara Falls. It is curious to note that a substance so useful and so harmless as common salt should be made out of two such refractory and dangerous elements as chlorine and sodium. Both of these elements, standing by themselves, seem to be out of harmony with nature, but when combined there are few substances that serve a better purpose.
These great salt beds that are found to exist in England and America and other parts of the world were undoubtedly deposited from the water of the ocean at some stage in the formation of the earth"s crust. It is well known that sea water is exceedingly saline; 300 gallons of sea water will produce a bushel of salt. Undoubtedly beds of salt are also formed by inland lakes, such as the Great Salt Lake in Utah. Only about 2.7 per cent. of ocean water is salt, while the water of the Great Salt Lake of Utah contains about 17 per cent. When there is so much salt in water that it is called a saturated solution, salt crystals will form and drop to the bottom, which process will in time build up under a large body of salt water a great bed of rock salt.
The water in all rivers and springs contains salt to a certain degree, and where it runs into a basin like that of a lake with no outlet, through the process of evaporation pure water is being constantly carried off, leaving the salt behind. It is easy to see that if this process is kept up long enough the water will become in time a saturated solution, when crystallization sets in and precipitation follows, accounting for the deposits of rock salt.
AIR.
CHAPTER VI.
THE ATMOSPHERE.
Meteorology is a science that at one time included astronomy, but now it is restricted to the weather, seasons, and all phenomena that are manifested in the atmosphere in its relation to heat, electricity, and moisture, as well as the laws that govern the ever-varying conditions of the circ.u.mambient air of our globe. The air is made up chiefly of oxygen and nitrogen, in the proportions of about twenty-one parts of oxygen and seventy-nine parts nitrogen by volume, and by weight about twenty-three parts oxygen and seventy-seven of nitrogen. These gases exist in the air as free gases and not chemically combined. The air is simply a mixture of these two gases.
There is a difference between a mixture and a compound. In a mixture there is no chemical change in the molecules of the substances mixed. In a compound there has been a rearrangement of the atoms, new molecules are formed, and a new substance is the result.
About 99-1/2 per cent. of air is oxygen and nitrogen and one-half per cent. is chiefly carbon dioxide. Carbon dioxide is a product of combustion, decay, and animal exhalation. It is poison to the animal, but food for the vegetable. However, the proportion in the air is so small that its baneful influence upon animal life is reduced to a minimum. The nitrogen is an inert, odorless gas, and its use in the air seems to be to dilute it, so that man and animals can breathe it. If all the nitrogen were extracted from the air and only the oxygen left to breathe, all animal life would be stimulated to death in a short time.
The presence of the nitrogen prevents too much oxygen from being taken into the system at once. I suppose men and animals might have been so organized that they could breathe pure oxygen without being hurt, but they were not, for some reason, made that way.
Air contains more or less moisture in the form of vapor; this subject, however, will be discussed more fully under the head of evaporation. The air at sea-level weighs fifteen pounds to the square inch, and if the whole envelope of air were h.o.m.ogeneous--the same in character--it would reach only about five miles high. But as it becomes gradually rarefied as we ascend, it probably extends in a very thin state to a height of eighty or ninety miles; at least, at that height we should find a more perfect vacuum than can be produced by artificial means. The weight of all the air on the globe would be 11-2/3 trillion pounds if no deduction had to be made for s.p.a.ce filled by mountains and land above sea-level.
As it is, the whole bulk weighs something less than the above figures.
As we have said, the air envelopes the globe to a height at sea-level of eighty or ninety miles, gradually thinning out into the ether that fills all interstellar s.p.a.ce. We live and move on the bottom of a great ocean of air. The birds fly in it just as the fish swim in the ocean of water.
Both are transparent and both have weight. Water in the condensed state is heavier than the air and will seek the lowest places, but when vaporized, as in the process of evaporation, it is lighter than air and floats upward. In the vapor state it is transparent like steam. If you study a steam jet you will notice that for a short distance after it issues from the boiler it is transparent, but soon it condenses into cloud.
If we could see inside of a boiler in which steam had been generated, all the s.p.a.ce not occupied with water would seem to be vacant, since steam before it is condensed is as transparent as the air. We will, however, speak of this subject more fully under the head of evaporation and cloud formation. It is not enough that we have the air in which we live and move, with all of its properties, as we have described: something more is needed which is absolutely essential both to animal and vegetable life--and this essential is motion. If the air remained perfectly still with no lateral movement or upward and downward currents of any kind, we should have a perfectly constant condition of things subjected only to such gradual changes as the advancing and receding seasons would produce owing to the change in the angle of the sun"s rays. No cloud would ever form, no rain would ever fall, and no wind would ever blow. It is of the highest importance not only that the wind shall blow, but that comparatively sudden changes of temperature take place in the atmosphere, in order that vegetation as well as animal life may exist upon the surface of the globe. The only place where animal life could exist would be in the great bodies of water, and it is even doubtful if water could remain habitable unless there were means provided for constant circulation--motion.
The mobility of the atmosphere is such that the least influence that changes its balance will put it in motion. While we can account in a general way for atmospheric movements, there are many problems relating to the details that are unsolved. We find that even the "weather man"
makes mistakes in his prognostications; so true is this that it is never safe to plan a picnic for to-morrow based upon the predictions of to-day. The chief difficulty in the way of solving the great problems relating to the sudden changes in the weather and temperature lies in the fact that two-thirds or more of the earth"s surface is covered with water; thus making it impossible to establish stations for observation that would be evenly distributed all over the earth"s surface. Enough is known, however, to make the study of meteorology a most wonderfully interesting subject.
We have already stated that air is composed of a mixture of oxygen and nitrogen chiefly, with a small amount of carbon dioxide. So far as the life and health of the animal is concerned we could get along without this latter substance, but it seems to be a necessity in the growth of vegetation. There are other things in the air which, while they are unnecessary for breathing purposes, it will be well for us to understand, as some of them are things to be avoided rather than inhaled.
As before mentioned, air contains moisture, which is a very variable quant.i.ty. In a cold day in winter it is not more than one-thousandth part, while in a warm day in summer it may equal one-fortieth of the quant.i.ty of air in a given s.p.a.ce. There is also a small amount of ammonia, perhaps not over one-sixty-millionth. Oxygen also exists in the air in very small quant.i.ties in another form called ozone. One way to produce ozone is by pa.s.sing an electric spark through air. Anyone who has operated a Holtz machine has noticed a peculiar smell attending the disruptive discharges, which is the odor of ozone. It is what chemists call an allotropic form of oxygen, just as the diamond, graphite, and charcoal are all different forms of carbon, and yet the chemical differences are scarcely traceable. It is more stimulating to breathe than oxygen and is probably produced by lightning discharges.
As has been before stated, the oxygen of the air is consumed by all processes of combustion, and in this we include the breathing of men and animals and the decay of vegetable matter, as well as the more active combustion arising from fires. A grown person consumes something over 400 gallons of oxygen per day, and it is estimated that all the fires on the earth consume in a century as much oxygen as is contained in the air over an area of seventy miles square. All of these processes are throwing into the air carbon dioxide (carbonic acid), which, however, is offset by the power of vegetation to absorb it, where the carbon is retained and forms a part of the woody fiber and pure oxygen is given back into the air. By this process the normal conditions of the air are maintained.
One decimeter (nearly 4 inches) square of green leaves will decompose in one hour seven cubic centimeters of carbon dioxide, if the sun is shining on them; in the shade the same area will absorb about three in the same time.
There is another substance in the form of vegetable germs in the air called bacteria. At one time these were supposed to be low forms of animal life, but it is now determined that they are the lowest forms of vegetable germs. Bacteria is the general or generic name for a large cla.s.s of germs, many of them disease germs. By a.n.a.lysis of the air in different locations and in different parts of the country it has been determined that on the ocean and on the mountain tops these germs average only one to each cubic yard of air. In the streets of the average city there are 3000 of them to the cubic yard, while in other places where there is sickness, as in a hospital ward, there may be as many as 80,000 to the cubic yard. These facts go to prove what has long been well known, that the air of a city furnishes many more fruitful sources for disease than that of the country. Some forms of bacterial germs are not considered harmful, and they probably perform even a useful service in the economy of nature. Within certain limits, other things being equal, the higher one"s dwelling is located above the common level the purer will be the air. This rule, however, has its limits, as the oxygen of the air is heavier than the nitrogen, so that the air at very great alt.i.tudes has not the same proportion of oxygen to nitrogen that it has at a lower level. An a.n.a.lysis that was made some years ago of the air on the west sh.o.r.e of Lake Michigan, especially that section where the bluffs are high, shows that it compares favorably with that of any other portion of the United States.
In view of the foregoing, it is of the highest importance to the sanitary condition of any city, town, or village that it be not too compactly built. If more than a certain number of people occupy a given area, it is absolutely impossible to preserve perfect sanitary conditions. And there ought to be a State law, especially for all suburban towns, which are the homes and sleeping places for large numbers of business men who spend their days in the foul air of the city, stipulating that the houses shall be not less than a certain distance apart. Oxygen is the great purifier of the blood, and if one does not get enough of it he suffers even though he breathes no impurities. The power to resist the effects of bad air is much greater when one is awake and active than when asleep, and this is why it is more important to sleep in pure air than to be in it during our waking hours. It is best, however, to be in good air all of the time. By pure air I do not mean pure oxygen, but the right mixture of the two gases that make air. Too much of a good thing is often worse than not enough.
Pure food to eat, pure water to drink, and pure air to breathe would soon be the financial ruin of a large cla.s.s of doctors.
CHAPTER VII.
AIR TEMPERATURE.
The most recent definition of heat is that it is a mode of motion; not movement of a ma.s.s of substance, but movement of its ultimate particles.
It has been determined by experiment that the ability of any substance to absorb heat depends upon the number of atoms it contains, rather than its bulk or its weight.
It has also been stated that the atmosphere at sea-level weighs about fifteen pounds to the square inch, which means that a column of air one inch square extending from sea-level upward to the extreme limit of the atmosphere weighs fifteen pounds. The density of the air decreases as we ascend. Each successive layer, as we ascend, is more and more expanded, and consequently has a less and less number of air molecules in a given s.p.a.ce. Therefore the capacity of the air for holding heat decreases as we go higher.
We deduce from these facts that the higher we go the colder it becomes; and this we find to be the case. Whoever has ascended a high mountain has had no difficulty in determining two things. One is that the air is very much colder than at sea-level, and the other that it is very much lighter in weight. We find it difficult, when we first reach the summit, to take enough of oxygen into our lungs to carry on the natural operations of the bodily functions. To overcome this difficulty, if we remain at this alt.i.tude for a considerable time, we shall find that our lungs have expanded, so as to make up in quant.i.ty what is lacking in quality.
If a man lives for a long time at an alt.i.tude of 10,000 feet he will find that his lungs are so expanded that he experiences some difficulty when he comes down to sea-level. And the reverse is true with one whose lungs are adapted to the conditions we find at sea-level, when he ascends to a higher alt.i.tude. There is a constant endeavor on the part of nature to adapt both animal and vegetable life to the surroundings.
While no exact formula has been established as to the rate of decrement of temperature as we ascend, we may say that it decreases about one degree in every 300 or 400 feet of ascent. There is no exact way of arriving at this, as in ascending a mountain the temperature will be more or less affected by local conditions. If we go up in a balloon we have to depend upon the barometer as a means of measuring alt.i.tude, which, owing to the varying atmospheric conditions, is not a reliable mode of measurement. It is easily understood that a cubic foot of air at sea-level will contain a great many more atoms than a cubic foot of air will at the top of a high mountain; or, to state it in another way, a cubic foot of air at sea-level will occupy much more than a cubic foot of s.p.a.ce 10,000 feet higher up. Suppose, then, that the amount of heat held in a cubic foot of air at sea-level remained the same, as related to the number of atoms. In its ascent we shall find that at a high alt.i.tude the same number of atoms that were held at sea-level in a cubic foot have been distributed over a so much larger s.p.a.ce that the sensible heat is greatly diminished or diluted, so to speak. It was an old notion that heat would hide itself away in fluids under a name called by scientists latent heat. This theory has been exploded, however, by modern investigation.
If we place some substance that will inflame at a low temperature in the bottom of what is called a fire syringe (which is nothing but a cylinder bored out smoothly, with a piston head nicely fitted to it, so that it will be air-tight) and then suddenly condense the air in the syringe by shoving the plunger to the bottom, we can inflame the substance which has been placed in the bottom of the cylinder. In this operation the heat that was distributed through the whole body of air, that was contained in the cylinder before it was compressed, is now condensed into a small s.p.a.ce. If we withdraw the plunger immediately, before the heat has been taken up by the walls of the syringe, we shall find the air of the same temperature as before the plunger was thrust down. This, however, does not take into account any heat that was generated by friction.
Let us further ill.u.s.trate the phenomenon by another experiment. If we suddenly compress a cubic foot of air at ordinary pressure into a cubic inch of s.p.a.ce, that cubic inch will be very hot because it contains all the heat that was distributed through the entire cubic foot before the compression took place. Now let it remain compressed until the heat has radiated from it, as it soon will, and the air becomes of the same temperature as the surrounding air. What ought to happen if then we should suddenly allow this cubic inch of air to expand to its normal pressure, when it will occupy a cubic foot of s.p.a.ce?
Inasmuch as we allowed the heat to escape from it when in the condensed form, when it expands it will be very cold, because the heat of the cubic inch, now reduced to the normal temperature of the surrounding air, is distributed over a cubic foot of s.p.a.ce.
This is precisely what takes place when heated air at the surface of the earth (which is condensed to a certain extent) rises to the higher regions of the atmosphere. There is a gradual expansion as it ascends, and consequently a gradual cooling, because a given amount of heat is being constantly distributed over a greater amount of s.p.a.ce. At an alt.i.tude of forty-five miles it will have expanded about 25,000 times, which will bring the temperature down to between 200 and 300 degrees below zero.
When we get beyond the limits of the atmosphere we get into the region of absolute cold, because heat is atomic motion, and there can be no atomic motion where there are no atoms.
We have now traced the atmosphere up to the point where it shades off into the ether that is supposed to fill all interplanetary s.p.a.ce. As Dryden says:
There fields of light and liquid ether flow, Purg"d from the pond"rous dregs of earth below.