The relation is also invariable, even when the substance of which the cathode is formed is changed or one gas is subst.i.tuted for another. It is, on the average, a thousand times greater than the corresponding relation in electrolysis. As experiment has shown, in all the circ.u.mstances where it has been possible to effect measurements, the equality of the charges carried by all corpuscules, ions, atoms, etc., we ought to consider that the charge of the electron is here, again, that of a univalent ion in electrolysis, and therefore that its ma.s.s is only a small fraction of that of the atom of hydrogen, viz., of the order of about a thousandth part. This is the same result as that to which we were led by the study of flames.
The thorough examination of the cathode radiation, then, confirms us in the idea that every material atom can be dissociated and will yield an electron much smaller than itself--and always identical whatever the matter whence it comes,--the rest of the atom remaining charged with a positive quant.i.ty equal and contrary to that borne by the electron. In the present case these positive ions are no doubt those that we again meet with in the ca.n.a.l rays. Professor Wien has shown that their ma.s.s is really, in fact, of the order of the ma.s.s of atoms.
Although they are all formed of identical electrons, there may be various cathode rays, because the velocity is not exactly the same for all electrons. Thus is explained the fact that we can separate them and that we can produce a sort of spectrum by the action of the magnet, or, again, as M. Deslandres has shown in a very interesting experiment, by that of an electrostatic field. This also probably explains the phenomena studied by M. Villard, and previously pointed out.
-- 2. RADIOACTIVE SUBSTANCES
Even in ordinary conditions, certain substances called radioactive emit, quite outside any particular reaction, radiations complex indeed, but which pa.s.s through fairly thin layers of minerals, impress photographic plates, excite fluorescence, and ionize gases. In these radiations we again find electrons which thus escape spontaneously from radioactive bodies.
It is not necessary to give here a history of the discovery of radium, for every one knows the admirable researches of M. and Madame Curie.
But subsequent to these first studies, a great number of facts have acc.u.mulated for the last six years, among which some people find themselves a little lost. It may, perhaps, not be useless to indicate the essential results actually obtained.
The researches on radioactive substances have their starting-point in the discovery of the rays of uranium made by M. Becquerel in 1896. As early as 1867 Niepce de St Victor proved that salts of uranium impressed photographic plates in the dark; but at that time the phenomenon could only pa.s.s for a singularity attributable to phosph.o.r.escence, and the valuable remarks of Niepce fell into oblivion. M. Becquerel established, after some hesitations natural in the face of phenomena which seemed so contrary to accepted ideas, that the radiating property was absolutely independent of phosph.o.r.escence, that all the salts of uranium, even the uranous salts which are not phosph.o.r.escent, give similar radiant effects, and that these phenomena correspond to a continuous emission of energy, but do not seem to be the result of a storage of energy under the influence of some external radiation. Spontaneous and constant, the radiation is insensible to variations of temperature and light.
The nature of these radiations was not immediately understood,[32] and their properties seemed contradictory. This was because we were not dealing with a single category of rays. But amongst all the effects there is one which const.i.tutes for the radiations taken as a whole, a veritable process for the measurement of radioactivity. This is their ionizing action on gases. A very complete study of the conductivity of air under the influence of rays of uranium has been made by various physicists, particularly by Professor Rutherford, and has shown that the laws of the phenomenon are the same as those of the ionization due to the action of the Rontgen rays.
[Footnote 32: In his work on _L"evolution de la Matiere_, M. Gustave Le Bon recalls that in 1897 he published several notes in the Academie des Sciences, in which he a.s.serted that the properties of uranium were only a particular case of a very general law, and that the radiations emitted did not polarize, and were akin by their properties to the X rays.]
It was natural to ask one"s self if the property discovered in salts of uranium was peculiar to this body, or if it were not, to a more or less degree, a general property of matter. Madame Curie and M.
Schmidt, independently of each other, made systematic researches in order to solve the question; various compounds of nearly all the simple bodies at present known were thus pa.s.sed in review, and it was established that radioactivity was particularly perceptible in the compounds of uranium and thorium, and that it was an atomic property linked to the matter endowed with it, and following it in all its combinations. In the course of her researches Madame Curie observed that certain pitchblendes (oxide of uranium ore, containing also barium, bis.m.u.th, etc.) were four times more active (activity being measured by the phenomenon of the ionization of the air) than metallic uranium. Now, no compound containing any other active metal than uranium or thorium ought to show itself more active than those metals themselves, since the property belongs to their atoms. It seemed, therefore, probable that there existed in pitchblendes some substance yet unknown, in small quant.i.ties and more radioactive than uranium.
M. and Madame Curie then commenced those celebrated experiments which brought them to the discovery of radium. Their method of research has been justly compared in originality and importance to the process of spectrum a.n.a.lysis. To isolate a radioactive substance, the first thing is to measure the activity of a certain compound suspected of containing this substance, and this compound is chemically separated.
We then again take in hand all the products obtained, and by measuring their activity anew, it is ascertained whether the substance sought for has remained in one of these products, or is divided among them, and if so, in what proportion. The spectroscopic reaction which we may use in the course of this separation is a thousand times less sensitive than observation of the activity by means of the electrometer.
Though the principle on which the operation of the concentration of the radium rests is admirable in its simplicity, its application is nevertheless very laborious. Tons of uranium residues have to be treated in order to obtain a few decigrammes of pure salts of radium.
Radium is characterised by a special spectrum, and its atomic weight, as determined by Madame Curie, is 225; it is consequently the higher h.o.m.ologue of barium in one of the groups of Mendeleef. Salts of radium have in general the same chemical properties as the corresponding salts of barium, but are distinguished from them by the differences of solubility which allow of their separation, and by their enormous activity, which is about a hundred thousand times greater than that of uranium.
Radium produces various chemical and some very intense physiological reactions. Its salts are luminous in the dark, but this luminosity, at first very bright, gradually diminishes as the salts get older. We have here to do with a secondary reaction correlative to the production of the emanation, after which radium undergoes the transformations which will be studied later on.
The method of a.n.a.lysis founded by M. and Madame Curie has enabled other bodies presenting sensible radioactivity to be discovered. The alkaline metals appear to possess this property in a slight degree.
Recently fallen snow and mineral waters manifest marked action. The phenomenon may often be due, however, to a radioactivity induced by radiations already existing in the atmosphere. But this radioactivity hardly attains the ten-thousandth part of that presented by uranium, or the ten-millionth of that appertaining to radium.
Two other bodies, polonium and actinium, the one characterised by the special nature of the radiations it emits and the other by a particular spectrum, seem likewise to exist in pitchblende. These chemical properties have not yet been perfectly defined; thus M.
Debierne, who discovered actinium, has been able to note the active property which seems to belong to it, sometimes in lanthanum, sometimes in neodynium.[33] It is proved that all extremely radioactive bodies are the seat of incessant transformations, and even now we cannot state the conditions under which they present themselves in a strictly determined form.
[Footnote 33: Polonium has now been shown to be no new element, but one of the transformation products of radium. Radium itself is also thought to be derived in some manner, not yet ascertained, from uranium. The same is the case with actinium, which is said to come in the long run from uranium, but not so directly as does radium. All this is described in Professor Rutherford"s _Radioactive Transformations_ (London, 1906).--ED.]
-- 3. THE RADIATION OF THE RADIOACTIVE BODIES AND THE EMANATION
To acquire exact notions as to the nature of the rays emitted by the radioactive bodies, it was necessary to try to cause magnetic or electric forces to act on them so as to see whether they behaved in the same way as light and the X rays, or whether like the cathode rays they were deviated by a magnetic field. This work was effected by Professor Giesel, then by M. Becquerel, Professor Rutherford, and by many other experimenters after them. All the methods which have already been mentioned in principle have been employed in order to discover whether they were electrified, and, if so, by electricity of what sign, to measure their speed, and to ascertain their degree of penetration.
The general result has been to distinguish three sorts of radiations, designated by the letters alpha, beta, gamma.
The alpha rays are positively charged, and are projected at a speed which may attain the tenth of that of light; M.H. Becquerel has shown by the aid of photography that they are deviated by a magnet, and Professor Rutherford has, on his side, studied this deviation by the electrical method. The relation of the charge to the ma.s.s is, in the case of these rays, of the same order as in that of the ions of electrolysis. They may therefore be considered as exactly a.n.a.logous to the ca.n.a.l rays of Goldstein, and we may attribute them to a material transport of corpuscles of the magnitude of atoms. The relatively considerable size of these corpuscles renders them very absorbable. A flight of a few millimetres in a gas suffices to reduce their number by one-half. They have great ionizing power.
The beta rays are on all points similar to the cathode rays; they are, as M. and Madame Curie have shown, negatively charged, and the charge they carry is always the same. Their size is that of the electrons, and their velocity is generally greater than that of the cathode rays, while it may become almost that of light. They have about a hundred times less ionizing power than the alpha rays.
The gamma rays were discovered by M. Villard.[34] They may be compared to the X rays; like the latter, they are not deviated by the magnetic field, and are also extremely penetrating. A strip of aluminium five millimetres thick will stop the other kinds, but will allow them to pa.s.s. On the other hand, their ionizing power is 10,000 times less than that of the alpha rays.
[Footnote 34: This is admitted by Professor Rutherford (_Radio-Activity_, Camb., 1904, p. 141) and Professor Soddy (_Radio-Activity_, London, 1904, p. 66). Neither Mr Whetham, in his Recent _Development of Physical Science_ (London, 1904) nor the Hon. R.J. Strutt in _The Becquerel Rays_ (London, same date), both of whom deal with the historical side of the subject, seem to have noticed the fact.--ED.]
To these radiations there sometimes are added in the course of experiments secondary radiations a.n.a.logous to those of M. Sagnac, and produced when the alpha, beta, or gamma rays meet various substances.
This complication has often led to some errors of observation.
Phosph.o.r.escence and fluorescence seem especially to result from the alpha and beta rays, particularly from the alpha rays, to which belongs the most important part of the total energy of the radiation.
Sir W. Crookes has invented a curious little apparatus, the spinthariscope, which enables us to examine the phosph.o.r.escence of the blende excited by these rays. By means of a magnifying gla.s.s, a screen covered with sulphide of zinc is kept under observation, and in front of it is disposed, at a distance of about half a millimetre, a fragment of some salt of radium. We then perceive mult.i.tudes of brilliant points on the screen, which appear and at once disappear, producing a scintillating effect. It seems probable that every particle falling on the screen produces by its impact a disturbance in the neighbouring region, and it is this disturbance which the eye perceives as a luminous point. Thus, says Sir W. Crookes, each drop of rain falling on the surface of still water is not perceived as a drop of rain, but by reason of the slight splash which it causes at the moment of impact, and which is manifested by ridges and waves spreading themselves in circles.
The various radioactive substances do not all give radiations of identical const.i.tution. Radium and thorium possess in somewhat large proportions the three kinds of rays, and it is the same with actinium.
Polonium contains especially alpha rays and a few gamma rays.[35] In the case of uranium, the alpha rays have extremely slight penetrating power, and cannot even impress photographic plates. But the widest difference between the substances proceeds from the emanation. Radium, in addition to the three groups of rays alpha, beta, and gamma, disengages continuously an extremely subtle emanation, seemingly almost imponderable, but which may be, for many reasons, looked upon as a vapour of which the elastic force is extremely feeble.
[Footnote 35: It has now been shown that polonium when freshly separated emits beta rays also; see Dr Logeman"s paper in _Proceedings of the Royal Society_, A., 6th September 1906.--ED.]
M. and Madame Curie discovered as early as 1899 that every substance placed in the neighbourhood of radium, itself acquired a radioactivity which persisted for several hours after the removal of the radium.
This induced radioactivity seems to be carried to other bodies by the intermediary of a gas. It goes round obstacles, but there must exist between the radium and the substance a free and continuous s.p.a.ce for the activation to take place; it cannot, for instance, do so through a wall of gla.s.s.
In the case of compounds of thorium Professor Rutherford discovered a similar phenomenon; since then, various physicists, Professor Soddy, Miss Brooks, Miss Gates, M. Danne, and others, have studied the properties of these emanations.
The substance emanated can neither be weighed nor can its elastic force be ascertained; but its transformations may be followed, as it is luminous, and it is even more certainly characterised by its essential property, i.e. its radioactivity. We also see that it can be decanted like a gas, that it will divide itself between two tubes of different capacity in obedience to the law of Mariotte, and will condense in a refrigerated tube in accordance with the principle of Watt, while it even complies with the law of Gay-Lussac.
The activity of the emanation vanishes quickly, and at the end of four days it has diminished by one-half. If a salt of radium is heated, the emanation becomes more abundant, and the residue, which, however, does not sensibly diminish in weight, will have lost all its radioactivity, and will only recover it by degrees. Professor Rutherford, notwithstanding many different attempts, has been unable to make this emanation enter into any chemical reaction. If it be a gaseous body, it must form part of the argon group, and, like its other members, be perfectly inert.
By studying the spectrum of the gas disengaged by a solution of salt of radium, Sir William Ramsay and Professor Soddy remarked that when the gas is radioactive there are first obtained rays of gases belonging to the argon family, then by degrees, as the activity disappears, the spectrum slowly changes, and finally presents the characteristic aspect of helium.
We know that the existence of this gas was first discovered by spectrum a.n.a.lysis in the sun. Later its presence was noted in our atmosphere, and in a few minerals which happen to be the very ones from which radium has been obtained. It might therefore have been the case that it pre-existed in the gases extracted from radium; but a remarkable experiment by M. Curie and Sir James Dewar seems to show convincingly that this cannot be so. The spectrum of helium never appears at first in the gas proceeding from pure bromide of radium; but it shows itself, on the other hand, very distinctly, after the radioactive transformations undergone by the salt.
All these strange phenomena suggest bold hypotheses, but to construct them with any solidity they must be supported by the greatest possible number of facts. Before admitting a definite explanation of the phenomena which have their seat in the curious substances discovered by them, M. and Madame Curie considered, with a great deal of reason, that they ought first to enrich our knowledge with the exact and precise facts relating to these bodies and to the effects produced by the radiations they emit.
Thus M. Curie particularly set himself to study the manner in which the radioactivity of the emanation is dissipated, and the radioactivity that this emanation can induce on all bodies. The radioactivity of the emanation diminishes in accordance with an exponential law. The constant of time which characterises this decrease is easily and exactly determined, and has a fixed value, independent of the conditions of the experiment as well as of the nature of the gas which is in contact with the radium and becomes charged with the emanation. The regularity of the phenomenon is so great that it can be used to measure time: in 3985 seconds[36] the activity is always reduced one-half.
[Footnote 36: According to Professor Rutherford, in 3.77 days.--ED]
Radioactivity induced on any body which has been for a long time in presence of a salt of radium disappears more rapidly. The phenomenon appears, moreover, more complex, and the formula which expresses the manner in which the activity diminishes must contain two exponentials.
To find it theoretically we have to imagine that the emanation first deposits on the body in question a substance which is destroyed in giving birth to a second, this latter disappearing in its turn by generating a third. The initial and final substances would be radioactive, but the intermediary one, not. If, moreover, the bodies acted on are brought to a temperature of over 700, they appear to lose by volatilisation certain substances condensed in them, and at the same time their activity disappears.
The other radioactive bodies behave in a similar way. Bodies which contain actinium are particularly rich in emanations. Uranium, on the contrary, has none.[37] This body, nevertheless, is the seat of transformations comparable to those which the study of emanations reveals in radium; Sir W. Crookes has separated from uranium a matter which is now called uranium X. This matter is at first much more active than its parent, but its activity diminishes rapidly, while the ordinary uranium, which at the time of the separation loses its activity, regains it by degrees. In the same way, Professors Rutherford and Soddy have discovered a so-called thorium X to be the stage through which ordinary thorium has to pa.s.s in order to produce its emanation.[38]
[Footnote 37: Professor Rutherford has lately stated that uranium may possibly produce an emanation, but that its rate of decay must be too swift for its presence to be verified (see _Radioactive Transformations_, p. 161).--ED.]
[Footnote 38: An actinium X was also discovered by Professor Giesel (_Jahrbuch d. Radioaktivitat_, i. p. 358, 1904). Since the above was written, another product has been found to intervene between the X substance and the emanation in the case of actinium and thorium. They have been named radio-actinium and radio-thorium respectively.--ED.]
It is not possible to give a complete table which should, as it were, represent the genealogical tree of the various radioactive substances.
Several authors have endeavoured to do so, but in a premature manner; all the affiliations are not at the present time yet perfectly known, and it will no doubt be acknowledged some day that identical states have been described under different names.[39]
[Footnote 39: Such a table is given on p. 169 of Rutherford"s _Radioactive Transformations_.--ED.]
-- 4. THE DISAGGREGATION OF MATTER AND ATOMIC ENERGY